CHAPTER 3: Enantiomers
Enhanced diagrams for many of the structures / schemes / figures are given below:
Structure 3.1
Structures 3.2-3.3
Structure 3.4
Structure 3.5
Structure 3.6
Structure 3.7
Structure 3.8
Scheme 3.1
(
R
)-3.11
(
R
)-3.9
(
R
)-3.12
(
R,S
)-3.13
(
S
)-3.11
(
S
)-3.9
(
R
)-3.12
(
S,S
)-3.13
Figure 3.1: Reaction Pathway / Energy Diagrams for the Reaction of Alcohol 3.9 with a: Acid Chloride 3.10; and b: Acid Chloride 3.12.
Figure 3.2: The Interaction between Plane Polarized Light and an Enantiomerically Pure Solution.
Figure 3.3: A Schematic Representation of a Polarimeter.
Figure 3.5: The Relationship between Circularly and Plane Polarized Light.
(
S
)-3.14
(
R
)-3.14
Figure 3.8: Interaction of Enantiomers with a Receptor Containing a: Two and b: Three Binding Sites.
The two enantiomers of compound
3.15
in
Scheme 3.2
Figure 3.9: Energy Diagram for the Formation of Enantiomeric Products from Achiral Precursors.
3.17
Structures 3.20 and 3.21
Structure 3.22
Structures 3.24 to 3.26
Structures 3.27 and 3.28
Structure 3.29
Structures 3.30-3.32
Structure 3.33
Structure 3.34
Structure 3.35
Structures 3.36-3.38
3.38
enantiomer of 3.38
Structure 3.34
Structure 3.39-40
Structure 3.42-3.44
Structures 3.45-3.48
3.45
3.46
3.47
3.48
Structures 3.49-3.52
3.49
3.50b
3.50c
3.51
3.52
Structures 3.53/3.55
3.53
3.55
Structures 3.57-3.59
3.57
3.58
3.59
Structures 3.60a,b
Structures 3.61a,b
3.61a
3.61b
Structures 3.62-3.65
3.62
3.63
3.64
3.65
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