|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Major
Goals in Polyoxometalate
Synthesis
|
|
|
|
|
|
|
|
|
|
Predictable,
high-yield reactions
|
|
|
|
|
|
|
|
|
|
|
•
systematic variation of
structure
|
|
|
|
|
|
|
|
|
|
|
•
systematic incorporation of
functionality
|
|
|
|
|
|
|
|
|
•
systematic variation of
reactivity
|
|
|
|
|
|
|
|
|
|
Systematic
reactivity studies
|
|
|
|
|
|
|
|
|
|
|
•
structure/property
relationships
|
|
|
|
|
|
|
|
|
|
|
•
composition/property
relationships
|
|
|
|
|
|
|
|
|
|
•
mechanistic understanding of aggregation
& degradation
|
|
|
|
|
|
|
|
|
|
|
Design
& synthesis of specific structures
with specific properties
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|